Aubrey said:
In recent years the air has always been bad in the summer with very high levels of CO2. We have never been able to explain the change.
Fact 20: Over the last 50 years, the concentration of carbon dioxide in the atmosphere has increase by 30% due to burning of fossil fuels and greenhouse gas emissions like carbon dioxide, nitrous oxide and other gases, trapping more heat in the lower atmosphere.
So maybe more of that carbon dioxide is being absorbed by rainwater & washed into caves. Those with a dynamic stream (e.g.Swildons) will carry the gas through the system, whilst less established streams (e.g. Cuckoo Cleeves & Manor Farm) may back up, allowing more gas to be released.
Changes in agricultural practice (manures & chemicals used) & more livestock per acre will also have had an effect & may also have increased the microbial fauna beneath the fields.
Cavers entering caves with poor circulation will also increase levels.
The following is taken from:
http://nhvss.org.au/wp-content/publications/Foul%20Air%20Rescue%20Australia.pdf
TYPES OF FOUL AIR IN CAVES Speleologists have categorised cave ?Foul Air? in three main types.
1. ?Foul Air Type 1?, is produced when CO2 is introduced into the cave atmosphere from ground water. This occurs because CO2 is absorbed by the ground water as it passes through surface soil containing high concentrations of the gas, due to the decay of vegetation. The resulting weak carbonic acid percolates through the rock strata and enters the cave system, usually taking part in the calcite deposition cycle before the CO2 is liberated to the cave atmosphere. In this instance it takes the addition of five percent CO2 to reduce the O2 level by one percent.
2. In ?Foul Air Type 2? the CO2 is a by-product of organic and micro-organism metabolism or respiration by fauna such as bats or humans. In this instance the oxygen concentration is reduced in proportion to the increase in CO2. The N2 concentration stays constant.
3. ?Foul Air Type 3?, is a cave atmosphere which has resulted from the introduction of other gasses, such as methane and nitrogen and the non-respiratory uptake of O2 as well as CO2 stripping by water. Another example is ?stink damp? so named because it often contains hydrogen sulfide and the O2 is significantly more depleted than in ?Type 2?. Foul air consisting strictly of ?Type 3? is rare in Australian caves, although some samples collected at Bungonia do suggest a few caves contain atmospheres partly influenced by this mechanism.
Mike