Two Novel Designs for Carbide Lamps - from an article written 20 years ago
PLEASE this is not serious!!!!
with Benefits for Cave Conservation
Carbide lamps operate by producing flammable acetylene gas from the reaction between calcium carbide and water, calcium oxide (lime) also being generated:-
CaC2 + H2O = C2H2 + CaO
There is an instantaneous further reaction of the calcium oxide produced with more water to produce what is often called slaked lime:-
CaO + H2O = Ca(OH)2
The acetylene gas burns in air with a hot yellow flame; inclusion in the gas of oxygen before the jet results in better combustion and a much less luminous light blue flame. This is of no use to the caver, but is of use to welders as we have just reinvented the oxy-acetylene blowtorch. The other product of the reaction, calcium hydroxide, is the substance seen in unsightly piles around caves. Ultimately this basic material will react with the nearest available acid, so-called carbonic acid, better visualised as carbon dioxide in damp air:-
Ca(OH)2 + CO2 = CaCO3 + H2O
The first product of the reaction is calcium carbonate, also found as chalk, marble, and in certain circumstances, limestone. The second is water, which you will remember was added to the carbide in the first place to produce acetylene. The three equations can therefore be combined:-
CaC2 + CO2 + H2O = C2H2 + CaCO3
Calcium carbonate either as a solid or as its solution in water is fundamental to caves, so it would therefore not be unreasonable to discard it as carbide waste. This technique would obviate the necessity to remove spent carbide (calcium hydroxide) from caves or to leave it lying around. All that is required then is a carbide lamp that operates on carbonated water!
Two models are proposed for acetylene generators operating under the principles outlined above.
The FLIXBOROUGH Generator
Taking as the norm the standard generator holding 200g of carbide, some 137.5g of carbon dioxide is required. Now the measurement of carbon dioxide in water is carried out using the antiquated units of 'volumes'. A 1 volume solution is just that; for instance one pint of carbon dioxide gas dissolved in one pint of water. Draught beer contains carbon dioxide at about 1 vol., keg beer about 1.3, bottled beer about 2.4 and very fizzy soft drinks up to about 4 vols. The 137.5g of carbon dioxide occupies a volume of 70 litres at normal temperature and pressure. A rigid polythene reservoir of reasonable thickness is suitable for carrying carbonated water at 5 vols. and need therefore have a capacity of a mere 14 litres. To allow for refills of carbide on longer trips, this should be increased to 25 litres, when it can easily be back mounted with shoulder straps. A self-draining valve of the type used in compressed air line water traps enables the carbonate slurry to be discharged from the base of the generator down the leg of the user at random intervals.
The CHERNOBYL Generator
The somewhat bulky apparatus described above has been superceded by another development. To obtain the same amount of carbon dioxide in a smaller space, the gas can be compressed in a metal pressure vessel until it becomes a liquid. Its density is then similar to that of water. Injection of liquid carbon dioxide onto the carbide via a venturi from a water reservoir then achieves the same effect as previously described but in a far smaller package. The generator walls need to be about ¼" thick and constructed of high grade metal (e.g. 316 grade stainless steel). The generator is charged with carbon dioxide from a cylinder before a trip, and scores over the FLIXBOROUGH in that the water can be topped up during use without disturbing the carbon dioxide supply. In addition to its rather high capital cost and need for an annual pressure test, the CHERNOBYL design is unpopular due to the high insurance premiums demanded from the users.
Both types of generator benefit from traditional ones in having pressure fed water supplies; this stops the irritating changes in flame size that occur when bending and crawling.
These advanced designs represent the greatest steps forward in carbide lamp design since the original invention. They are also a positive contribution to cave conservation. I would be pleased to discuss further constructional details with interested parties, and to advise on suitable policies to ensure that next of kin are not left helpless in the likely event of a nasty accident during use.
CMG