I may completely wrong here, but my feeling is that you'd be considerably better off sucking than blowing.
I'll try and explain myself, and to make this easier I'll pretend that your CO2 is in fact water. So your dig face is at a low point, which contains a pool or sump of water.
(I realise that this is far from a perfect analogy since CO2, being gaseous, will mix with air when there is any kind of turbulence, whereas water will clearly not! But still, there may be something in this.)
Ok, so imagine that you are blowing fresh air down your pipe into the bottom of that pool of water. All that happens is your fresh air rises up through the water and disappears back up the passage. Your nasty pool of water (or CO2) stays exactly where it was.
But what happens if you reverse the flow? The end of your pipe, being at the low point, will suck up only the dense water and carry it away, and the only possible result is that it will be replaced by fresh air flowing inwards along the passage. Hey presto, you remove your water (or CO2) and replace it with nice fresh air.
The real problem is that you need enough power to raise that dense water up the height difference required to get it out of the dig.
But this has got me thinking... in a situation where the 'water' was in fact
real water you might be able to set a syphon going. Now how good would that be if you could do the same with CO2?!?