Ocassional trips into Side mine used to be permitted courtesy of the colour works which, as has been correctly stated, is now closed. For a period of time, outflow from one of the colour works processes was vented into side mine, coating the place with a very liberal dose of red oxide (or something similar), which would then stain all your caving kit, and meant you left a significant tell-tale trail of red foot-prints on exiting the mine.
My understanding is that the current owners (Hights of Abraham IIRC) have spent a lot of money cleaning the site up, and would be none-too-pleased if it were covered in red dye again!
That said (again, IIRC) High tor grotto did not suffer the same fate and is relatively clean...?
Z